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41.
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以马来酸酐(MAH)和稀土异戊橡胶(IR)聚合液为主要原料,采用溶液接枝改性反应制备了马来酸酐接枝稀土异戊橡胶(IR-g-MAH)。以IR-g-MAH接枝率的测试方法为研究对象,对比直接滴定法和返滴法,并进一步优化直接滴定法的测试条件。实验结果表明,直接滴定法测试的结果准确度高、重复性好,且测试过程简单。其较优的测试条件为:水解试剂为乙醇,样品用量为0.2~0.5g,KOH-乙醇标准溶液浓度为0.02~0.06mol/L。 相似文献
43.
Yuxi Wang Weiduo Zhu Ke Lin Lanfeng Yuan Xiaoguo Zhou Shilin Liu 《Journal of Raman spectroscopy : JRS》2016,47(10):1231-1238
The micro‐structure of hydration shell of solute in water is significant for understanding the properties of aqueous solutions. However the spectra of hydration shell are difficult to be obtained. Herein, a novel Raman ratio spectra, which is obtained through dividing the Raman spectra of aqueous solutions from the spectrum of water, was applied to deduce the spectra of hydration shell of organic (acetone‐D6) and inorganic compounds (NaNO3, NaSCN, NaClO4, Na2SO4, NaCl) in water. Those spectra of the hydration shell were employed to study the micro‐structures of the first hydration shells of anions, the number of water molecules in the first hydration shell of free anions and acetone‐D6, and the aggregation behavior of ions in the concentrated aqueous NaNO3. The number of water molecules in the hydration shell was supported by our molecular dynamic simulations. The Raman ratio spectra can be widely employed to obtain the spectra of the first hydration shell, and it is helpful to understand the micro‐structure of aqueous solutions. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
44.
SPATIAL AND SEASONAL DISTRIBUTIONS OF ATMOSPHERIC CARBONACEOUS AEROSOLS IN PEARL RIVER DELTA REGION, CHINA 总被引:11,自引:0,他引:11
Concentrations and spatial distributions of organic carbon (OC) and elemental carbon (EC) in atmospheric particles were measured at 8 sites in four cities (Hong Kong, Guangzhou, Shenzhen and Zhuhai) of Pearl River Delta Region (PRDR), China during 2001 winter period and 2002 summer period. PM2.5 (particie diameter smaller than 2.5 um) and PM10 (particie diameter smaller than 10 um) samples were collected on pre-fired quartz filters with mini-volume samplers and analyzed using thermal optical reflectance (TOR) method. The average PM2.5and PM10 Ievel were 60.1 and 93.1 μg·m-3, respectively, with PM2.5 constituting 65.3% of the PM10 mass. The average OC and EC concentrations in PM2.5 were 12.0 and 5.1 μg·m-3, respectively, while those in PM10 were 16.0 and 6.5 μg·m-3, respectively. The carbo-naceous aerosol accounted for 37.2% of the PM2.5 and 32.8% of the PM10. The highest concentrations of OC and EC were observed at Guangzhou city in both vvinter and summer seasons. The average OC/EC ratios were 2. 相似文献
45.
通过求解采用ALE方法描述的运动坐标系Navier-Stokes方程组,分析均匀来流下雷诺
数为150的静止和流向振荡的圆柱绕流. 主要研究了强迫振荡频率和较大振幅比
(A/D=0.3-1.2)对圆柱升力、阻力变化特性以及涡脱落模态的影响. 研究表
明,流向振荡圆柱绕流存在多种涡脱落模态,如对称S以及反对称A-I, A-III,
A-IV等多种形式;比较研究结果,拓展了各模态下对应的锁定区域,并将其分为5个
子区;A-I模态中圆柱受力较以前所知更复杂;通过分析计算结果,发现最大加速度
比Af_{c}^{2}/Df_{s0}^{2}可能是涡脱落模态(尤其是对称S模态)最有效的控制参数. 相似文献
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通过对高性能 (AS系列 )固化剂与水泥的对比试验 ,研究其在天津软弱地基加固中适用性和优越性 ,并得出一套实用的固化剂加固软土地基的施工设计参数 相似文献
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A one-dimensional approximate analytical model, which preserves the main features of soil-crop-atmospheric hydrodynamics,
has been suggested for plant roots of low soil-root conductivity ratio (SRCR). The proposed approach involves physically based
concepts, such as mass balance equation, Darcy’s law, and related water uptake and plant transpiration functions. Two main
assumptions have been made to derive the analytical solution: (1) gravitational flow is adopted and (2) the uniform soil moisture
distribution within the root water activity zone is supposed. The mass balance equation in its integral form is solved by
the method of characteristics. This leads to the two functional equations for soil pressure head and root potential, which
can be solved simultaneously by using common software. The model has been further verified against the numerical one. The
model represents a reasonable compromise between the complicated mechanism of unsaturated water flow with root water uptake
(RWU) and still insufficient knowledge of the soil-plant-atmospheric continuum. It is able to account for temporal fluctuations
in root activity zone and provides a relatively simple algorithm for investigation of RWU-mechanism. Besides the theoretical
and applicative importance, this flow model yields water and velocity distributions within soil profile, and, thereby, constitutes
a preliminary step toward solution of contaminant transport problems in vadose zone.
Deceased 相似文献